Show simple item record

dc.contributor.authorVillada, Juan D.
dc.contributor.authorCarmona Vargas, Christian C.
dc.contributor.authorAlcides Ellena, Javier
dc.contributor.authorAyala, Alejandro P.
dc.contributor.authorRamírez Pradilla, Juan S.
dc.contributor.authorCombariza, M. Y.
dc.contributor.authorGalarza, Esperanza
dc.contributor.authorD'Vries, Richard Fernando
dc.contributor.authorChaur, Manuel N.
dc.date.accessioned2020-10-23T22:57:39Z
dc.date.available2020-10-23T22:57:39Z
dc.date.issued2020-08-25
dc.identifier.issn0022-4596
dc.identifier.urihttp://repository.usc.edu.co/handle/20.500.12421/4534
dc.description.abstractHerein we report the synthesis and structural characterization of a new Ni-bis(hydrazone) complex with the chemical formula [Ni2(L)2(Cl)2](Cl)2·2H2O (L ​= ​2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine). Suitable crystals for X-ray diffraction showed the supramolecular interactions of this complex to exhibit a helical structure coordinating two Ni2+ metal ions bounded by two 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine ligands. In addition, exploitation of the electrochemical properties by cyclic voltammetry, for this helicate, showed catalyzing ability for the reduction of H+ to H2.en_US
dc.language.isoenen_US
dc.publisherAcademic Press Inc.en_US
dc.subjectBis(hydrazones)en_US
dc.subjectCatalyzed hydrogen reductionen_US
dc.subjectNickel helicatesen_US
dc.subjectSupramolecular chemistryen_US
dc.titleSynthesis, characterization, and redox potential properties of a new double-stranded Ni-bis(hydrazone)-based helicateen_US
dc.typeArticleen_US


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record